Clickable 2,2‐bis(hydroxymethyl)propionic acid‐derived <scp> AB <sub>2</sub> </scp> monomers: Hyperbranched polyesters through the <scp>CuAAC</scp> cycloaddition (click) reaction
نویسندگان
چکیده
We present the synthesis and characterization of two aliphatic AB2 monomers derived from readily available 2,2-bis(hydroxymethyl)propionic acid containing one alkyne group azide functionalities. The distance between polymerizable groups differs in by insertion an additional carbon atom structure that addresses steric demand during polymerization. synthetic procedure for is relatively simple scalable, are able to polymerize through Copper(I)-catalyzed Azide-Alkyne Cycloaddition (CuAAC reaction). polymerization affords hyperbranched polymers good yields molecular weights moderate degrees branching. Copyright © 2021 John Wiley & Sons, Ltd.
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ژورنال
عنوان ژورنال: Journal of polymer science
سال: 2021
ISSN: ['1542-9385', '0098-1273']
DOI: https://doi.org/10.1002/pol.20210340